I know this is a really weird question, but the reason why I need to change the volume by using Rockbox (if it is possible) is that the soundcard manufacturer told me I can't control volume via their drivers because of legal issues with the chipset manufacturer, and also because I can't change volume on my headphones ^^.
If there's no easy solution like a cfg file, then that's okay. I just wanted to test out my iriver's optical output quality before I get my new external dac/amp which may come in about a week. I love Rockbox btw ^^.